The Merseysiders grabbed the winner 20 minutes from time in the quarter-final replay thanks to a fine individual goal by the Brazil international.
Two days ago, in the wake of the crushing 4-1 defeat to Arsenal which put a huge dent in the Reds' Champions League hopes, Coutinho had claimed: "Winning the cup would save our season."
Jordan Henderson split the Championship side's defence for Coutinho, who set himself before rifling his right-footer into the far corner.
Liverpool were very nearly denied victory at the death by Rovers goalkeeper Simon Eastwood, but were thankful to Simon Mignolet for making a vital stop.
Playmaker Coutinho's effort helped the seven-time winners reach their 24th FA Cup semi-final and set up a Wembley meeting with Villa on Sunday 19 April with only Arsenal (27), Manchester United (27) and Everton (25) having appeared in more.
The game was far from pretty but with Wembley tantalisingly close it was about getting the job done and Coutinho rose above all others to add the piece of class which did just that.
Blackburn's chances had been talked down due to the injury crisis which had effectively reduced them to 11 fit men, with 16-goal striker Rudy Gestede, nursing a hamstring injury, on the bench for emergencies.
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